flowtube Package
A Python package for transport and diffusion calculations in cylindrical flow reactors using the KPS method published in Knopf et al., Anal. Chem., 2015. The package is currently designed for coated wall reactor (CWR) and boat reactor analysis with plans to support aerosol flow reactors in future versions.
Author: Corey Pedersen
Documentation: https://flowtube.readthedocs.io/
Features
Flow Calculations: Flow rates, velocities, residence times, and Reynolds numbers.
Transport Properties: Dynamic viscosity and density
Diffusion Analysis: Binary diffusion coefficients, Péclet numbers, and mixing parameters
Uptake Modeling: Diffusion correction factors and uptake coefficient calculations
Support for Inserts: Handles coated cylindrical inserts within flow tubes
Support for Boats: Handles boat reactors which are placed inside of a flow tube and filled with an analyte solution.
Scientific Applications
This package is designed for atmospheric chemistry and aerosol research, particularly for:
Heterogeneous reaction kinetics studies
Uptake coefficient measurements
Flow reactor design and optimization
Transport phenomena analysis in laminar flow systems
Installation
pip install flowtube
Acronyms
sccm = standard cubic centimeter per minuteFT = flow tubeFR = flow rateMR = mixing ratioCWR = coated wall reactor
Assumptions
KPS method assumptions (Knopf et al., 2015):
The interacting gas species is a trace gas in the bulk flow
Laminar flow is established in the flow reactor
The gas temperature and viscosity are homogeneous
The axial diffusion velocity is negligible compared to bulk flow velocity
The amount of gas species taken up is small compared to its reservoir
There is an absence of gas-phase reactions impacting gas species concentration
Bibliography (more citations within package files)
Knopf, D.A., Pöschl, U., Shiraiwa, M., 2015. Radial Diffusion and Penetration of Gas Molecules and Aerosol Particles through Laminar Flow Reactors, Denuders, and Sampling Tubes. Anal. Chem. 87, 3746–3754. https://doi.org/10.1021/ac5042395